1st(1st leg) Reggina Calcio - Chievo Verona 2:2 (2:0)
2nd (2nd leg) Chievo Verona - Reggina Calcio 1:1 (1:0)
1st(1st leg): 08/11/2006 12:30 2nd (2nd leg): 30/11/2006 14:00 Winner: Chievo Verona
1st(1st leg) Empoli FC - Genoa CFC 1:0 (1:0)
2nd (2nd leg) Genoa CFC - Empoli FC 0:1 (0:1)
1st(1st leg): 08/11/2006 19:30 2nd (2nd leg): 06/12/2006 19:30 Winner: Empoli FC
1st(1st leg) Sampdoria - US Palermo 1:0 (0:0)
2nd (2nd leg) US Palermo - Sampdoria 2:3 (0:2)
1st(1st leg): 08/11/2006 19:30 2nd (2nd leg): 30/11/2006 20:00 Winner: Sampdoria
1st(1st leg) AC Milan - Brescia Calcio 4:2 (0:2)
2nd (2nd leg) Brescia Calcio - AC Milan 1:2 (1:2)
1st(1st leg): 08/11/2006 19:30 2nd (2nd leg): 28/11/2006 20:00 Winner: AC Milan
1st(1st leg) AC Arezzo - AS Livorno 2:1 (1:0)
2nd (2nd leg) AS Livorno - AC Arezzo 1:1 (1:0)
1st(1st leg): 08/11/2006 19:30 2nd (2nd leg): 06/12/2006 19:45 Winner: AC Arezzo
1st(1st leg) US Triestina - AS Roma 1:2 (0:1)
2nd (2nd leg) AS Roma - US Triestina 2:0 (2:0)
1st(1st leg): 08/11/2006 19:30 2nd (2nd leg): 29/11/2006 16:00 Winner: AS Roma
1st(1st leg) FC Messina - Inter 0:1 (0:1)
2nd (2nd leg) Inter - FC Messina 4:0 (2:0)
1st(1st leg): 09/11/2006 19:30 2nd (2nd leg): 29/11/2006 20:00 Winner: Inter
1st(1st leg) SSC Napoli - Parma FC 1:0 (0:0)
2nd (2nd leg) Parma FC - SSC Napoli 3:1 (1:0)
1st(1st leg): 09/11/2006 20:00 2nd (2nd leg): 07/12/2006 14:00 Winner: Parma FC