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| 24/08/2010 | 19:45 | Brechin City FC | - | Dundee FC | 3:1 (0:0, 2:2, 2:2) pso | |
| 19:45 | Heart of Midlothian | - | Elgin City | 4:0 (2:0) | ||
| 19:45 | Alloa Athletic | - | Aberdeen FC | 0:3 (0:2) | ||
| 19:45 | St. Johnstone FC | - | Greenock Morton FC | 2:0 (1:0) | ||
| 19:45 | Partick Thistle | - | Falkirk FC | 0:1 (0:0) | ||
| 19:45 | Raith Rovers | - | Hamilton Academical | 1:0 (0:0) | ||
| 19:45 | Dunfermline Athletic | - | Clyde FC | 3:2 (1:1) | ||
| 25/08/2010 | 19:45 | Kilmarnock FC | - | Airdrie United FC | 6:2 (2:1) | |
| 19:45 | Ross County FC | - | St. Mirren FC | 4:3 (0:1, 2:2, 3:3) pso | ||
| 19:45 | Inverness CT | - | Peterhead FC | 3:0 (2:0) | ||
| 19:45 | Queen Of The South | - | Forfar Athletic | 4:1 (2:0) |
