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| 31/07/2012 | 19:45 | Peterhead FC | - | Dundee FC | 1:4 (0:0, 0:0, 0:0) pso | |
| 04/08/2012 | 15:00 | Queen Of The South | - | Alloa Athletic | 5:2 (1:0) | |
| 15:00 | Stranraer FC | - | Livingston FC | 0:8 (0:3) | ||
| 15:00 | Raith Rovers | - | Berwick Rangers | 4:3 (1:1) | ||
| 15:00 | Stenhousemuir FC | - | Brechin City FC | 4:0 (1:0) | ||
| 15:00 | Montrose FC | - | Cowdenbeath FC | 2:1 (2:0) | ||
| 15:00 | Ayr United | - | Clyde FC | 6:1 (0:0) | ||
| 15:00 | Arbroath FC | - | Stirling Albion FC | 3:2 (0:1, 1:1, 1:1) pso | ||
| 15:00 | Hamilton Academical | - | Annan Athletic | 2:0 (0:0) | ||
| 15:00 | Falkirk FC | - | Elgin City | 2:0 (0:0) | ||
| 15:00 | Dumbarton FC | - | Albion Rovers | 2:0 (1:0) | ||
| 15:00 | Queen's Park FC | - | Airdrie United FC | 3:2 (0:0, 2:2) aet | ||
| 15:00 | Forfar Athletic | - | Partick Thistle | 0:2 (0:2) | ||
| 05/08/2012 | 15:00 | East Stirlingshire FC | - | Greenock Morton FC | 1:5 (1:3) | |
| 07/08/2012 | 19:45 | Rangers FC | - | East Fife FC | 4:0 (2:0) |
