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| 22/08/2012 | 19:30 | Greenock Morton FC | - | Aberdeen FC | 0:2 (0:0, 0:0) aet | |
| 28/08/2012 | 19:45 | Livingston FC | - | Dumbarton FC | 3:2 (1:1, 1:1) aet | |
| 19:45 | Ross County FC | - | Raith Rovers | 1:4 (0:2) | ||
| 19:45 | Kilmarnock FC | - | Stenhousemuir FC | 1:2 (0:2) | ||
| 19:45 | Queen Of The South | - | Hibernian FC | 2:0 (2:0) | ||
| 19:45 | Dunfermline Athletic | - | Montrose FC | 3:0 (2:0) | ||
| 19:45 | Hamilton Academical | - | Partick Thistle | 1:0 (0:0, 0:0) aet | ||
| 29/08/2012 | 19:45 | St. Mirren FC | - | Ayr United | 5:1 (4:1) | |
| 19:45 | Queen's Park FC | - | Dundee FC | 2:1 (1:1) | ||
| 19:45 | Arbroath FC | - | Inverness CT | 0:2 (0:1) | ||
| 30/08/2012 | 19:45 | Rangers FC | - | Falkirk FC | 3:0 (2:0) |
