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| 24/09/2013 | 19:45 | Celtic FC | - | Greenock Morton FC | 0:1 (0:0, 0:0) aet | |
| 19:45 | Dundee FC | - | Inverness CT | 0:1 (0:1) | ||
| 19:45 | Hamilton Academical | - | St. Johnstone FC | 0:3 (0:1) | ||
| 19:45 | Hibernian FC | - | Stranraer FC | 5:3 (3:1) | ||
| 25/09/2013 | 19:15 | Falkirk FC | - | Aberdeen FC | 0:5 (0:2) | |
| 19:45 | Dundee United | - | Partick Thistle | 4:1 (2:0) | ||
| 19:45 | Heart of Midlothian | - | Queen Of The South | 4:2 (1:1, 2:2, 3:3) pso | ||
| 19:45 | Livingston FC | - | Motherwell FC | 1:2 (0:1) |
