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| 1st(1st leg) | Rapid Bucureşti | - | Hamburger SV | 2:0 (1:0) | ||
| 2nd (2nd leg) | Hamburger SV | - | Rapid Bucureşti | 3:1 (2:0) | ||
| 1st(1st leg): 09/03/2006 15:00 | 2nd (2nd leg): 15/03/2006 18:00 | Winner: Rapid Bucureşti | ||||
| 1st(1st leg) | FC Steaua Bucureşti | - | Real Betis | 0:0 (0:0) | ||
| 2nd (2nd leg) | Real Betis | - | FC Steaua Bucureşti | 0:3 (0:0) | ||
| 1st(1st leg): 09/03/2006 17:00 | 2nd (2nd leg): 16/03/2006 20:30 | Winner: FC Steaua Bucureşti | ||||
| 1st(1st leg) | US Palermo | - | FC Schalke 04 | 1:0 (1:0) | ||
| 2nd (2nd leg) | FC Schalke 04 | - | US Palermo | 3:0 (1:0) | ||
| 1st(1st leg): 09/03/2006 17:00 | 2nd (2nd leg): 16/03/2006 19:30 | Winner: FC Schalke 04 | ||||
| 1st(1st leg) | Lille OSC | - | Sevilla FC | 1:0 (1:0) | ||
| 2nd (2nd leg) | Sevilla FC | - | Lille OSC | 2:0 (2:0) | ||
| 1st(1st leg): 09/03/2006 18:00 | 2nd (2nd leg): 15/03/2006 20:00 | Winner: Sevilla FC | ||||
| 1st(1st leg) | FC Basel | - | RC Strasbourg | 2:0 (1:0) | ||
| 2nd (2nd leg) | RC Strasbourg | - | FC Basel | 2:2 (1:2) | ||
| 1st(1st leg): 09/03/2006 19:15 | 2nd (2nd leg): 16/03/2006 17:00 | Winner: FC Basel | ||||
| 1st(1st leg) | Olympique Marseille | - | Zenit St. Petersburg | 0:1 (0:0) | ||
| 2nd (2nd leg) | Zenit St. Petersburg | - | Olympique Marseille | 1:1 (0:0) | ||
| 1st(1st leg): 09/03/2006 19:45 | 2nd (2nd leg): 16/03/2006 16:00 | Winner: Zenit St. Petersburg | ||||
| 1st(1st leg) | Udinese Calcio | - | Levski Sofia | 0:0 (0:0) | ||
| 2nd (2nd leg) | Levski Sofia | - | Udinese Calcio | 2:1 (0:1) | ||
| 1st(1st leg): 09/03/2006 19:45 | 2nd (2nd leg): 16/03/2006 16:30 | Winner: Levski Sofia | ||||
| 1st(1st leg) | Middlesbrough FC | - | AS Roma | 1:0 (1:0) | ||
| 2nd (2nd leg) | AS Roma | - | Middlesbrough FC | 2:1 (1:1) | ||
| 1st(1st leg): 09/03/2006 20:00 | 2nd (2nd leg): 15/03/2006 20:00 | Winner: Middlesbrough FC | ||||
