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| 1st(1st leg) | FC Steaua Bucureşti | - | Middlesbrough FC | 1:0 (1:0) | ||
| 2nd (2nd leg) | Middlesbrough FC | - | FC Steaua Bucureşti | 4:2 (1:2) | ||
| 1st(1st leg): 20/04/2006 18:45 | 2nd (2nd leg): 27/04/2006 20:00 | Winner: Middlesbrough FC | ||||
| 1st(1st leg) | FC Schalke 04 | - | Sevilla FC | 0:0 (0:0) | ||
| 2nd (2nd leg) | Sevilla FC | - | FC Schalke 04 | 1:0 (0:0, 0:0) aet | ||
| 1st(1st leg): 20/04/2006 19:30 | 2nd (2nd leg): 27/04/2006 20:30 | Winner: Sevilla FC | ||||
