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| 21/09/2011 | 13:00 | Titan Armyansk | - | Dnipro Dnipropetrovsk | 0:1 (0:0) | |
| 13:30 | FK Poltava | - | Karpaty Lviv | 0:1 (0:0) | ||
| 13:30 | Shakhtar Sverdlovsk | - | Shakhtar Donetsk | 0:2 (0:2) | ||
| 14:00 | MFK Mikolaiv | - | Vorskla Poltava | 0:2 (0:1) | ||
| 14:00 | Berehvideyk Berehove | - | Metalist Kharkiv | 0:3 (0:2) | ||
| 14:00 | FK Bukovina | - | FK Obolon | 2:1 (1:0) | ||
| 14:00 | FK Kremin | - | Dinamo Kiev | 2:3 (0:2) | ||
| 14:00 | Stal Dniprodzerzhynsk (old) | - | PFK Sevastopol | 2:1 (2:1) | ||
| 14:00 | Slovkhlib Slovyansk | - | Zorya Lugansk | 0:2 (0:1) | ||
| 14:30 | Arsenal Bila Tserkva | - | FK Krivbas (old) | 2:3 (1:1, 2:2) aet | ||
| 14:30 | Energetik Burshtin | - | Chernomorets Odessa | 0:1 (0:1) | ||
| 15:00 | Arsenal Kiev | - | PFK Oleksandriya | 5:0 (1:0) | ||
| 16:00 | PFC Sumy | - | Zirka Kirovograd | 4:3 (0:0, 1:1, 1:1) pso | ||
| 16:30 | Metalurh Donetsk | - | Tavriya Simferopol (1958-2014) | 2:0 (2:0) | ||
| 17:00 | Metalurg Zaporizhya | - | Hoverla-Zakarpattya Uzhgorod | 1:0 (0:0) | ||
| 17:00 | Volyn Lutsk | - | FK Illichivets | 7:1 (2:0) |
