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| 1st(1st leg) | Aragua FC | - | Deportivo Táchira | 1:0 (1:0) | ||
| 2nd (2nd leg) | Deportivo Táchira | - | Aragua FC | 2:2 (1:1) | ||
| 1st(1st leg): 11/05/2016 19:45 | 2nd (2nd leg): 15/05/2016 21:30 | Winner: Aragua FC | ||||
| 1st(1st leg) | Mineros de Guayana | - | Deportivo Anzoátegui | 0:1 (0:0) | ||
| 2nd (2nd leg) | Deportivo Anzoátegui | - | Mineros de Guayana | 3:1 (0:1) | ||
| 1st(1st leg): 11/05/2016 22:00 | 2nd (2nd leg): 14/05/2016 22:00 | Winner: Deportivo Anzoátegui | ||||
| 1st(1st leg) | Caracas FC | - | Deportivo La Guaira | 2:1 (1:0) | ||
| 2nd (2nd leg) | Deportivo La Guaira | - | Caracas FC | 0:1 (0:1) | ||
| 1st(1st leg): 12/05/2016 00:15 | 2nd (2nd leg): 15/05/2016 20:00 | Winner: Caracas FC | ||||
| 1st(1st leg) | Trujillanos FC | - | Zamora FC | 2:3 (1:2) | ||
| 2nd (2nd leg) | Zamora FC | - | Trujillanos FC | 0:1 (0:1) | ||
| 1st(1st leg): 13/05/2016 00:00 | 2nd (2nd leg): 15/05/2016 22:30 | Winner: Zamora FC | ||||
