Friendlies   M. W D L goals
  Away 1 1 0 0 3 : 0
  1 1 0 0 3 : 0
EURO Qualifiers   M. W D L goals
  at home 2 2 0 0 4 : 0
  Away 2 2 0 0 5 : 1
  4 4 0 0 9 : 1
overall   M. W D L goals
  at home 2 2 0 0 4 : 0
  Away 3 3 0 0 8 : 1
  Neutral Place 0 0 0 0 0 : 0
  5 5 0 0 12 : 1
Friendlies
2006 June Luxembourg - Ukraine 0:3 (0:0)
EURO Qualifiers
2019/2020 Group B Ukraine - Luxembourg 1:0 (1:0)
2019/2020 Group B Luxembourg - Ukraine 1:2 (1:1)
2014/2015 Group C Ukraine - Luxembourg 3:0 (0:0)
2014/2015 Group C Luxembourg - Ukraine 0:3 (0:1)

For games that were decided on penalties the score after 120 minutes will be included in the ranking