Champions League   M. W D L goals
  at home 2 2 0 0 3 : 1
  Away 2 0 1 1 1 : 2
  4 2 1 1 4 : 3
Europa League   M. W D L goals
  at home 1 0 0 1 2 : 4
  Away 1 0 0 1 1 : 3
  2 0 0 2 3 : 7
Cup Winners Cup   M. W D L goals
  Neutral Place 1 0 1 0 0 : 0
  1 0 1 0 0 : 0
overall   M. W D L goals
  at home 3 2 0 1 5 : 5
  Away 3 0 1 2 2 : 5
  Neutral Place 1 0 1 0 0 : 0
  7 2 2 3 7 : 10
Champions League
2002/2003 Intermediate Gr. B Valencia CF - Arsenal FC 2:1 (1:0)
2002/2003 Intermediate Gr. B Arsenal FC - Valencia CF 0:0 (0:0)
2000/2001 Quarter-finals Valencia CF - Arsenal FC 1:0 (0:0)
2000/2001 Quarter-finals Arsenal FC - Valencia CF 2:1 (0:1)
Europa League
2018/2019 Semi-finals Valencia CF - Arsenal FC 2:4 (1:1)
2018/2019 Semi-finals Arsenal FC - Valencia CF 3:1 (2:1)
Cup Winners Cup
1979/1980 Final Valencia CF - Arsenal FC 5:4 (0:0, 0:0, 0:0) pso

For games that were decided on penalties the score after 120 minutes will be included in the ranking