Champions League   M. W D L goals
  at home 2 0 2 0 1 : 1
  Away 2 1 0 1 2 : 3
  4 1 2 1 3 : 4
Europa League   M. W D L goals
  at home 1 0 1 0 1 : 1
  Away 1 0 0 1 0 : 2
  2 0 1 1 1 : 3
overall   M. W D L goals
  at home 3 0 3 0 2 : 2
  Away 3 1 0 2 2 : 5
  Neutral Place 0 0 0 0 0 : 0
  6 1 3 2 4 : 7
Champions League
2010/2011 Round of 16 FC Schalke 04 - Valencia CF 3:1 (1:1)
2010/2011 Round of 16 Valencia CF - FC Schalke 04 1:1 (1:0)
2007/2008 Group B Valencia CF - FC Schalke 04 0:0 (0:0)
2007/2008 Group B FC Schalke 04 - Valencia CF 0:1 (0:0)
Europa League
1996/1997 Quarter-finals Valencia CF - FC Schalke 04 1:1 (1:1)
1996/1997 Quarter-finals FC Schalke 04 - Valencia CF 2:0 (1:0)

For games that were decided on penalties the score after 120 minutes will be included in the ranking