Champions League   M. W D L goals
  at home 3 0 2 1 0 : 2
  Away 3 0 2 1 1 : 2
  6 0 4 2 1 : 4
Europa League   M. W D L goals
  Neutral Place 1 0 1 0 1 : 1
  1 0 1 0 1 : 1
overall   M. W D L goals
  at home 3 0 2 1 0 : 2
  Away 3 0 2 1 1 : 2
  Neutral Place 1 0 1 0 1 : 1
  7 0 5 2 2 : 5
Champions League
2021/2022 Group F Villarreal CF - Manchester United 0:2 (0:0)
2021/2022 Group F Manchester United - Villarreal CF 2:1 (0:0)
2008/2009 Group E Villarreal CF - Manchester United 0:0 (0:0)
2008/2009 Group E Manchester United - Villarreal CF 0:0 (0:0)
2005/2006 Group D Manchester United - Villarreal CF 0:0 (0:0)
2005/2006 Group D Villarreal CF - Manchester United 0:0 (0:0)
Europa League
2020/2021 Final Villarreal CF - Manchester United 11:10 (1:0, 1:1, 1:1) pso

For games that were decided on penalties the score after 120 minutes will be included in the ranking