| #1 | 10/11/1963 | Italy | - | USSR | 1:1 | ||||
| #2 | 19/03/1966 | France | - | Italy | 0:0 | ||||
| #3 | 18/06/1966 | Italy | - | Austria | 1:0 | ||||
| #4 | 01/11/1966 | Italy | - | USSR | 1:0 | ||||
| #5 | 26/11/1966 | Italy | - | Romania | 3:1 | ||||
| #6 | 22/03/1967 | Cyprus | - | Italy | 0:2 |  |
|||
| #7 | 27/03/1967 | Italy | - | Portugal | 1:1 | ||||
| #8 | 01/11/1967 | Italy | - | Cyprus | 5:0 | ||||
| #9 | 18/11/1967 | Switzerland | - | Italy | 2:2 | ||||
| #10 | 23/12/1967 | Italy | - | Switzerland | 4:0 | |
|||
| #11 | 06/04/1968 | Bulgaria | - | Italy | 3:2 | ||||
| #12 | 20/04/1968 | Italy | - | Bulgaria | 2:0 | |
|||
| #13 | 05/06/1968 | Italy | - | USSR | 0:0 aet | ||||
| #14 | 08/06/1968 | Italy | - | Yugoslavia | 1:1 aet | |
|||
| #15 | 10/06/1968 | Italy | - | Yugoslavia | 2:0 | ||||
| #16 | 23/10/1968 | Wales | - | Italy | 0:1 | ||||
| #17 | 01/01/1969 | Mexico | - | Italy | 2:3 | ||||
| #18 | 24/05/1969 | Italy | - | Bulgaria | 0:0 | ||||
| #19 | 04/11/1969 | Italy | - | Wales | 4:1 | ||||
| #20 | 22/11/1969 | Italy | - | GDR | 3:0 | |
|||
| #21 | 21/02/1970 | Spain | - | Italy | 2:2 | ||||
| #22 | 10/05/1970 | Portugal | - | Italy | 1:2 | ||||
| #23 | 03/06/1970 | Italy | - | Sweden | 1:0 | |
|||
| #24 | 06/06/1970 | Uruguay | - | Italy | 0:0 | ||||
| #25 | 11/06/1970 | Italy | - | Israel | 0:0 | ||||
| #26 | 14/06/1970 | Italy | - | Mexico | 4:1 | ||||
| #27 | 17/06/1970 | Italy | - | Germany | 4:3 aet |  |
|||
| #28 | 21/06/1970 | Brazil | - | Italy | 4:1 | ||||
| #29 | 17/10/1970 | Switzerland | - | Italy | 1:1 | ||||
| #30 | 31/10/1970 | Austria | - | Italy | 1:2 | ||||
| #31 | 08/12/1970 | Italy | - | Ireland | 3:0 | ||||
| #32 | 09/06/1971 | Sweden | - | Italy | 0:0 | ||||
| #33 | 29/04/1972 | Italy | - | Belgium | 0:0 |
Italy