| #1 | 12/05/1963 | Italy | - | Brazil | 3:0 | ||||
| #2 | 09/06/1963 | Austria | - | Italy | 0:1 | ||||
| #3 | 13/10/1963 | USSR | - | Italy | 2:0 | ||||
| #4 | 10/11/1963 | Italy | - | USSR | 1:1 | ||||
| #5 | 14/12/1963 | Italy | - | Austria | 1:0 | ||||
| #6 | 11/04/1964 | Italy | - | CSSR | 0:0 | ||||
| #7 | 04/11/1964 | Italy | - | Finland | 6:1 | ||||
| #8 | 13/03/1965 | Germany | - | Italy | 1:1 | ||||
| #9 | 18/04/1965 | Poland | - | Italy | 0:0 | ||||
| #10 | 09/11/1965 | Scotland | - | Italy | 1:0 | ||||
| #11 | 14/06/1966 | Italy | - | Bulgaria | 6:1 | ||||
| #12 | 18/06/1966 | Italy | - | Austria | 1:0 | ||||
| #13 | 19/07/1966 | North Korea | - | Italy | 1:0 | ||||
| #14 | 01/11/1966 | Italy | - | USSR | 1:0 |  |
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| #15 | 26/11/1966 | Italy | - | Romania | 3:1 | ||||
| #16 | 22/03/1967 | Cyprus | - | Italy | 0:2 | ||||
| #17 | 27/03/1967 | Italy | - | Portugal | 1:1 | ||||
| #18 | 25/06/1967 | Romania | - | Italy | 0:1 | ||||
| #19 | 20/04/1968 | Italy | - | Bulgaria | 2:0 | ||||
| #20 | 08/06/1968 | Italy | - | Yugoslavia | 1:1 aet | ||||
| #21 | 10/06/1968 | Italy | - | Yugoslavia | 2:0 |
Italy