| #1 | 29/11/1959 | Italy | - | Hungary | 1:1 | ||||
| #2 | 06/01/1960 | Italy | - | Switzerland | 3:0 | ||||
| #3 | 10/12/1960 | Italy | - | Austria | 1:2 | ||||
| #4 | 25/04/1961 | Italy | - | Northern Ireland | 3:2 | ||||
| #5 | 24/05/1961 | Italy | - | England | 2:3 | ||||
| #6 | 15/06/1961 | Italy | - | Argentina | 4:1 |  |
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| #7 | 15/10/1961 | Israel | - | Italy | 2:4 | ||||
| #8 | 04/11/1961 | Italy | - | Israel | 6:0 | ||||
| #9 | 05/05/1962 | Italy | - | France | 2:1 | ||||
| #10 | 02/06/1962 | Chile | - | Italy | 2:0 | ||||
| #11 | 07/06/1962 | Italy | - | Switzerland | 3:0 | |
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| #12 | 11/11/1962 | Austria | - | Italy | 1:2 | ||||
| #13 | 14/12/1963 | Italy | - | Austria | 1:0 | ||||
| #14 | 04/11/1964 | Italy | - | Finland | 6:1 | ||||
| #15 | 05/12/1964 | Italy | - | Denmark | 3:1 | ||||
| #16 | 01/05/1965 | Italy | - | Wales | 4:1 | ||||
| #17 | 16/06/1965 | Sweden | - | Italy | 2:2 | ||||
| #18 | 23/06/1965 | Finland | - | Italy | 0:2 | ||||
| #19 | 27/06/1965 | Hungary | - | Italy | 2:1 | ||||
| #20 | 01/11/1965 | Italy | - | Poland | 6:1 | |
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| #21 | 07/12/1965 | Italy | - | Scotland | 3:0 | |
Italy