1. Round 01/09/1990 Real Madrid - CD Castellón 1:0
2. Round 07/09/1990 Sevilla FC - Real Madrid 2:0
3. Round 14/09/1990 Real Madrid - RCD Mallorca 3:0
4. Round 21/09/1990 Real Zaragoza - Real Madrid 1:3 Goal
5. Round 29/09/1990 Real Madrid - Cádiz CF 2:1
6. Round 07/10/1990 Real Sociedad - Real Madrid 1:1
7. Round 14/10/1990 Real Madrid - CD Logroñés 0:0
8. Round 21/10/1990 Real Oviedo - Real Madrid 0:0
9. Round 28/10/1990 Real Burgos - Real Madrid 2:1 yellow card
10. Round 03/11/1990 Real Madrid - Espanyol Barcelona 2:1 yellow card
11. Round 16/11/1990 Valencia CF - Real Madrid 2:1 yellow card
12. Round 24/11/1990 Real Madrid - Real Betis 3:0
13. Round 30/11/1990 Real Valladolid - Real Madrid 0:1
14. Round 08/12/1990 Real Madrid - CD Tenerife 3:0 yellow card
15. Round 14/12/1990 Athletic Bilbao - Real Madrid 1:0
16. Round 29/12/1990 Real Madrid - CA Osasuna 0:4
17. Round 05/01/1991 Sporting Gijón - Real Madrid 0:2
19. Round 18/01/1991 FC Barcelona - Real Madrid 2:1
20. Round 26/01/1991 CD Castellón - Real Madrid 0:3 Goal
21. Round 02/02/1991 Real Madrid - Sevilla FC 7:0
27. Round 23/03/1991 Real Madrid - Real Oviedo 1:1
29. Round 06/04/1991 Espanyol Barcelona - Real Madrid 3:1 Goal
30. Round 13/04/1991 Real Madrid - Valencia CF 4:0 Goal
31. Round 19/04/1991 Real Betis - Real Madrid 1:3
32. Round 27/04/1991 Real Madrid - Real Valladolid 1:0
33. Round 04/05/1991 CD Tenerife - Real Madrid 0:1
36. Round 24/05/1991 Real Madrid - Sporting Gijón 2:1
37. Round 01/06/1991 Atlético Madrid - Real Madrid 0:3
38. Round 07/06/1991 Real Madrid - FC Barcelona 1:0