| #1 | 07/06/1962 | Italy | - | Switzerland | 3:0 |  |
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| #2 | 11/11/1962 | Austria | - | Italy | 1:2 | ||||
| #3 | 02/12/1962 | Italy | - | Turkey | 6:0 | ||||
| #4 | 12/05/1963 | Italy | - | Brazil | 3:0 | |
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| #5 | 09/06/1963 | Austria | - | Italy | 0:1 | ||||
| #6 | 13/10/1963 | USSR | - | Italy | 2:0 | ||||
| #7 | 10/11/1963 | Italy | - | USSR | 1:1 | ||||
| #8 | 14/12/1963 | Italy | - | Austria | 1:0 | ||||
| #9 | 11/04/1964 | Italy | - | CSSR | 0:0 | ||||
| #10 | 04/11/1964 | Italy | - | Finland | 6:1 | |
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| #11 | 05/12/1964 | Italy | - | Denmark | 3:1 | |
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| #12 | 13/03/1965 | Germany | - | Italy | 1:1 | ||||
| #13 | 18/04/1965 | Poland | - | Italy | 0:0 | ||||
| #14 | 01/05/1965 | Italy | - | Wales | 4:1 | ||||
| #15 | 16/06/1965 | Sweden | - | Italy | 2:2 | ||||
| #16 | 23/06/1965 | Finland | - | Italy | 0:2 | ||||
| #17 | 27/06/1965 | Hungary | - | Italy | 2:1 | ||||
| #18 | 01/11/1965 | Italy | - | Poland | 6:1 | ||||
| #19 | 09/11/1965 | Scotland | - | Italy | 1:0 | ||||
| #20 | 07/12/1965 | Italy | - | Scotland | 3:0 | ||||
| #21 | 14/06/1966 | Italy | - | Bulgaria | 6:1 | ||||
| #22 | 18/06/1966 | Italy | - | Austria | 1:0 | ||||
| #23 | 22/06/1966 | Italy | - | Argentina | 3:0 | ||||
| #24 | 29/06/1966 | Italy | - | Mexico | 5:0 | |
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| #25 | 13/07/1966 | Italy | - | Chile | 2:0 | ||||
| #26 | 16/07/1966 | USSR | - | Italy | 1:0 | ||||
| #27 | 19/07/1966 | North Korea | - | Italy | 1:0 | ||||
| #28 | 27/03/1967 | Italy | - | Portugal | 1:1 | ||||
| #29 | 25/06/1967 | Romania | - | Italy | 0:1 |
Italy