| #1 | 10/05/1964 | Switzerland | - | Italy | 1:3 | ||||
| #2 | 04/11/1964 | Italy | - | Finland | 6:1 | ||||
| #3 | 05/12/1964 | Italy | - | Denmark | 3:1 | ||||
| #4 | 01/05/1965 | Italy | - | Wales | 4:1 |  |
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| #5 | 16/06/1965 | Sweden | - | Italy | 2:2 | ||||
| #6 | 23/06/1965 | Finland | - | Italy | 0:2 | ||||
| #7 | 27/06/1965 | Hungary | - | Italy | 2:1 | ||||
| #8 | 01/11/1965 | Italy | - | Poland | 6:1 | ||||
| #9 | 09/11/1965 | Scotland | - | Italy | 1:0 | ||||
| #10 | 07/12/1965 | Italy | - | Scotland | 3:0 | ||||
| #11 | 19/03/1966 | France | - | Italy | 0:0 | ||||
| #12 | 29/06/1966 | Italy | - | Mexico | 5:0 | ||||
| #13 | 13/07/1966 | Italy | - | Chile | 2:0 | ||||
| #14 | 16/07/1966 | USSR | - | Italy | 1:0 | ||||
| #15 | 22/03/1967 | Cyprus | - | Italy | 0:2 | ||||
| #16 | 27/03/1967 | Italy | - | Portugal | 1:1 | ||||
| #17 | 08/06/1968 | Italy | - | Yugoslavia | 1:1 aet |
Italy