| #1 | 29/06/1966 | Italy | - | Mexico | 5:0 | ||||
| #2 | 25/06/1967 | Romania | - | Italy | 0:1 |  |
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| #3 | 06/04/1968 | Bulgaria | - | Italy | 3:2 | ||||
| #4 | 01/01/1969 | Mexico | - | Italy | 2:3 | ||||
| #5 | 05/01/1969 | Mexico | - | Italy | 1:1 | |
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| #6 | 29/03/1969 | GDR | - | Italy | 2:2 | ||||
| #7 | 24/05/1969 | Italy | - | Bulgaria | 0:0 | ||||
| #8 | 04/11/1969 | Italy | - | Wales | 4:1 | ||||
| #9 | 10/05/1970 | Portugal | - | Italy | 1:2 | ||||
| #10 | 03/06/1970 | Italy | - | Sweden | 1:0 | ||||
| #11 | 06/06/1970 | Uruguay | - | Italy | 0:0 | ||||
| #12 | 11/06/1970 | Italy | - | Israel | 0:0 | ||||
| #13 | 14/06/1970 | Italy | - | Mexico | 4:1 | ||||
| #14 | 17/06/1970 | Italy | - | Germany | 4:3 aet | ||||
| #15 | 21/06/1970 | Brazil | - | Italy | 4:1 | ||||
| #16 | 31/10/1970 | Austria | - | Italy | 1:2 | ||||
| #17 | 08/12/1970 | Italy | - | Ireland | 3:0 | ||||
| #18 | 20/02/1971 | Italy | - | Spain | 1:2 | ||||
| #19 | 10/05/1971 | Ireland | - | Italy | 1:2 | ||||
| #20 | 09/06/1971 | Sweden | - | Italy | 0:0 |  |
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| #21 | 25/09/1971 | Italy | - | Mexico | 2:0 | ||||
| #22 | 09/10/1971 | Italy | - | Sweden | 3:0 | ||||
| #23 | 20/11/1971 | Italy | - | Austria | 2:2 | ||||
| #24 | 03/03/1972 | Greece | - | Italy | 2:1 | ||||
| #25 | 13/05/1972 | Belgium | - | Italy | 2:1 |
Italy