| #1 | 24/05/1961 | Italy | - | England | 2:3 | ||||
| #2 | 15/06/1961 | Italy | - | Argentina | 4:1 | ||||
| #3 | 15/10/1961 | Israel | - | Italy | 2:4 |  |
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| #4 | 04/11/1961 | Italy | - | Israel | 6:0 | |
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| #5 | 27/03/1963 | Turkey | - | Italy | 0:1 | ||||
| #6 | 12/05/1963 | Italy | - | Brazil | 3:0 | ||||
| #7 | 09/06/1963 | Austria | - | Italy | 0:1 | ||||
| #8 | 13/10/1963 | USSR | - | Italy | 2:0 | ||||
| #9 | 14/12/1963 | Italy | - | Austria | 1:0 | ||||
| #10 | 10/05/1964 | Switzerland | - | Italy | 1:3 | |
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| #11 | 04/11/1964 | Italy | - | Finland | 6:1 | ||||
| #12 | 13/03/1965 | Germany | - | Italy | 1:1 | ||||
| #13 | 18/04/1965 | Poland | - | Italy | 0:0 | ||||
| #14 | 16/06/1965 | Sweden | - | Italy | 2:2 | ||||
| #15 | 19/03/1966 | France | - | Italy | 0:0 | ||||
| #16 | 18/06/1966 | Italy | - | Austria | 1:0 | ||||
| #17 | 01/11/1966 | Italy | - | USSR | 1:0 | ||||
| #18 | 26/11/1966 | Italy | - | Romania | 3:1 | ||||
| #19 | 22/03/1967 | Cyprus | - | Italy | 0:2 | ||||
| #20 | 27/03/1967 | Italy | - | Portugal | 1:1 | ||||
| #21 | 10/05/1971 | Ireland | - | Italy | 1:2 |  |
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| #22 | 25/09/1971 | Italy | - | Mexico | 2:0 | ||||
| #23 | 09/10/1971 | Italy | - | Sweden | 3:0 |
Italy