1. Round | 18/07/2022 | Petrolul Ploieşti | - | FC Voluntari | 0:1 | ||||
2. Round | 23/07/2022 | FC Voluntari | - | FC Botoşani | 0:1 | ||||
6. Round | 22/08/2022 | Farul Constanța | - | FC Voluntari | 2:1 | ||||
7. Round | 26/08/2022 | FC Voluntari | - | Universitatea Cluj | 0:0 | ||||
8. Round | 31/08/2022 | CFR Cluj | - | FC Voluntari | 4:0 | ||||
9. Round | 03/09/2022 | FC Voluntari | - | Rapid Bucureşti | 0:1 | ||||
15. Round | 22/10/2022 | FC Voluntari | - | Chindia Târgoviște | 0:3 | ||||
16. Round | 29/10/2022 | FC Voluntari | - | Petrolul Ploieşti | 0:1 | ||||
17. Round | 04/11/2022 | FC Botoşani | - | FC Voluntari | 0:1 | ||||
22. Round | 20/01/2023 | Universitatea Cluj | - | FC Voluntari | 2:1 | ||||
23. Round | 30/01/2023 | FC Voluntari | - | CFR Cluj | 0:1 | ||||
24. Round | 04/02/2023 | Rapid Bucureşti | - | FC Voluntari | 4:1 | ||||
25. Round | 12/02/2023 | FC Voluntari | - | FCSB | 1:2 | ||||
26. Round | 20/02/2023 | FC Universitatea Craiova | - | FC Voluntari | 2:1 | ||||
28. Round | 01/03/2023 | CS Mioveni | - | FC Voluntari | 0:3 | ||||
29. Round | 06/03/2023 | FC Voluntari | - | Argeș Pitești | 0:0 | ||||
30. Round | 13/03/2023 | Chindia Târgoviște | - | FC Voluntari | 1:1 |