| #1 | 15/05/1960 | Spain | - | England | 3:0 | ||||
| #2 | 26/10/1960 | England | - | Spain | 4:2 |  |
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| #3 | 30/10/1960 | Austria | - | Spain | 3:0 | ||||
| #4 | 02/04/1961 | Spain | - | France | 2:0 | ||||
| #5 | 19/04/1961 | Wales | - | Spain | 1:2 | ||||
| #6 | 18/05/1961 | Spain | - | Wales | 1:1 | ||||
| #7 | 11/06/1961 | Spain | - | Argentina | 2:0 | |
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| #8 | 12/11/1961 | Morocco | - | Spain | 0:1 | |
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| #9 | 23/11/1961 | Spain | - | Morocco | 3:2 | ||||
| #10 | 10/12/1961 | France | - | Spain | 1:1 | ||||
| #11 | 31/05/1962 | CSSR | - | Spain | 1:0 | ||||
| #12 | 03/06/1962 | Spain | - | Mexico | 1:0 | ||||
| #13 | 30/10/1963 | Northern Ireland | - | Spain | 0:1 | ||||
| #14 | 23/06/1966 | Spain | - | Uruguay | 1:1 | ||||
| #15 | 13/07/1966 | Argentina | - | Spain | 2:1 | ||||
| #16 | 15/07/1966 | Spain | - | Switzerland | 2:1 |
Spain