1. Round 01/09/1990 Real Valladolid - CA Osasuna 1:1
3. Round 14/09/1990 Real Valladolid - Atlético Madrid 0:0
4. Round 22/09/1990 FC Barcelona - Real Valladolid 1:0 yellow card
5. Round 29/09/1990 Real Valladolid - CD Castellón 0:0
15. Round 15/12/1990 Real Valladolid - Valencia CF 3:1
16. Round 29/12/1990 Real Betis - Real Valladolid 0:0
17. Round 05/01/1991 Real Burgos - Real Valladolid 0:1
18. Round 12/01/1991 Real Valladolid - CD Tenerife 6:2
19. Round 19/01/1991 Athletic Bilbao - Real Valladolid 0:1
20. Round 26/01/1991 CA Osasuna - Real Valladolid 2:1 yellow card
21. Round 02/02/1991 Real Valladolid - Sporting Gijón 0:0
22. Round 09/02/1991 Atlético Madrid - Real Valladolid 2:0 yellow card
23. Round 23/02/1991 Real Valladolid - FC Barcelona 1:5
24. Round 02/03/1991 CD Castellón - Real Valladolid 4:2
25. Round 09/03/1991 Real Valladolid - Sevilla FC 2:1 Goal
26. Round 16/03/1991 RCD Mallorca - Real Valladolid 0:0
27. Round 23/03/1991 Real Valladolid - Real Zaragoza 0:0
28. Round 30/03/1991 Cádiz CF - Real Valladolid 0:0
29. Round 06/04/1991 Real Valladolid - Real Sociedad 4:2
30. Round 13/04/1991 CD Logroñés - Real Valladolid 1:2
31. Round 20/04/1991 Real Valladolid - Real Oviedo 1:0
32. Round 27/04/1991 Real Madrid - Real Valladolid 1:0 yellow card
33. Round 04/05/1991 Real Valladolid - Espanyol Barcelona 2:0 yellow card
34. Round 11/05/1991 Valencia CF - Real Valladolid 2:0 yellow card
35. Round 18/05/1991 Real Valladolid - Real Betis 1:1
36. Round 25/05/1991 Real Valladolid - Real Burgos 1:0
37. Round 01/06/1991 CD Tenerife - Real Valladolid 1:0
38. Round 08/06/1991 Real Valladolid - Athletic Bilbao 1:0