| #1 | 19/04/1961 | Wales | - | Spain | 1:2 | ||||
| #2 | 18/05/1961 | Spain | - | Wales | 1:1 | ||||
| #3 | 12/11/1961 | Morocco | - | Spain | 0:1 | ||||
| #4 | 23/11/1961 | Spain | - | Morocco | 3:2 | ||||
| #5 | 10/12/1961 | France | - | Spain | 1:1 | ||||
| #6 | 13/06/1963 | Spain | - | Scotland | 2:6 | ||||
| #7 | 30/10/1963 | Northern Ireland | - | Spain | 0:1 | ||||
| #8 | 01/12/1963 | Spain | - | Belgium | 1:2 |  |
|||
| #9 | 11/03/1964 | Spain | - | Ireland | 5:1 | ||||
| #10 | 08/04/1964 | Ireland | - | Spain | 0:2 | ||||
| #11 | 17/06/1964 | Spain | - | Hungary | 2:1 aet | ||||
| #12 | 21/06/1964 | Spain | - | USSR | 2:1 | ||||
| #13 | 15/11/1964 | Portugal | - | Spain | 2:1 | ||||
| #14 | 05/05/1965 | Ireland | - | Spain | 1:0 | ||||
| #15 | 08/05/1965 | Scotland | - | Spain | 0:0 |  |
|||
| #16 | 27/10/1965 | Spain | - | Ireland | 4:1 | ||||
| #17 | 10/11/1965 | Spain | - | Ireland | 1:0 | ||||
| #18 | 08/12/1965 | Spain | - | England | 0:2 | ||||
| #19 | 23/06/1966 | Spain | - | Uruguay | 1:1 | ||||
| #20 | 13/07/1966 | Argentina | - | Spain | 2:1 | ||||
| #21 | 15/07/1966 | Spain | - | Switzerland | 2:1 | ||||
| #22 | 20/07/1966 | Germany | - | Spain | 2:1 | ||||
| #23 | 03/04/1968 | England | - | Spain | 1:0 | ||||
| #24 | 08/05/1968 | Spain | - | England | 1:2 | ||||
| #25 | 23/02/1969 | Belgium | - | Spain | 2:1 |
Spain