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| 09/01/1966 | Royal Tilleur FC | - | Royal Beerschot AC | 1:1 | ||
| Sint-Truidense VV | - | Cercle Sportif Brugeois | 1:0 | |||
| Racing White Brussels | - | KAA Gent | 6:1 | |||
| KV Mechelen | - | Daring Club de Bruxelles | 1:0 | |||
| FC Brugeois | - | RSC Anderlecht | 0:1 | |||
| FC Beringen | - | RFC Liège | 1:0 | |||
| Berchem Sport | - | Lierse SK | 0:1 | |||
| Royal Antwerp FC | - | Standard Liège | 1:3 |
| » Tables | Home | Away | First round | Second round |
| # | Team | M. | W | D | L | goals | Dif. | Pt. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
RSC Anderlecht | 16 | 13 | 1 | 2 | 39:9 | 30 | 27:5 |
| 2 |
|
Sint-Truidense VV | 16 | 13 | 1 | 2 | 28:11 | 17 | 27:5 |
| 3 |
|
Royal Beerschot AC | 16 | 10 | 4 | 2 | 23:13 | 10 | 24:8 |
| 4 |
|
Standard Liège | 16 | 8 | 4 | 4 | 25:12 | 13 | 20:12 |
| 5 |
|
KV Mechelen | 16 | 8 | 2 | 6 | 19:16 | 3 | 18:14 |
| 6 |
|
RFC Liège | 16 | 6 | 4 | 6 | 28:27 | 1 | 16:16 |
| 7 |
|
Royal Antwerp FC | 16 | 6 | 4 | 6 | 24:24 | 0 | 16:16 |
| 8 |
|
KAA Gent | 16 | 6 | 4 | 6 | 27:35 | -8 | 16:16 |
| 9 |
|
Royal Tilleur FC | 16 | 6 | 4 | 6 | 16:24 | -8 | 16:16 |
| 10 |
|
FC Brugeois | 16 | 4 | 6 | 6 | 25:21 | 4 | 14:18 |
| 11 |
|
Berchem Sport | 16 | 4 | 4 | 8 | 14:23 | -9 | 12:20 |
| 12 |
|
Daring Club de Bruxelles | 16 | 4 | 4 | 8 | 14:13 | 1 | 12:20 |
| 13 |
|
Lierse SK | 16 | 3 | 5 | 8 | 11:25 | -14 | 11:21 |
| 14 |
|
Racing White Brussels | 16 | 4 | 3 | 9 | 19:26 | -7 | 11:21 |
| 15 |
|
FC Beringen | 16 | 4 | 2 | 10 | 14:30 | -16 | 10:22 |
| 16 |
|
Cercle Sportif Brugeois | 16 | 1 | 4 | 11 | 7:24 | -17 | 6:26 |
