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| 1st(1st leg) | Atlético Mineiro | - | Santos FC | 0:0 (0:0) | ||
| 2nd (2nd leg) | Santos FC | - | Atlético Mineiro | 1:2 (1:1) | ||
| 1st(1st leg): 15/05/2019 23:15 | 2nd (2nd leg): 07/06/2019 00:00 | Winner: Atlético Mineiro | ||||
| 1st(1st leg) | Corinthians SP | - | Flamengo RJ | 0:1 (0:0) | ||
| 2nd (2nd leg) | Flamengo RJ | - | Corinthians SP | 1:0 (0:0) | ||
| 1st(1st leg): 16/05/2019 01:30 | 2nd (2nd leg): 05/06/2019 01:30 | Winner: Flamengo RJ | ||||
| 1st(1st leg) | Fluminense RJ | - | Cruzeiro | 1:1 (0:0) | ||
| 2nd (2nd leg) | Cruzeiro | - | Fluminense RJ | 3:1 (0:1, 2:2) pso | ||
| 1st(1st leg): 16/05/2019 01:30 | 2nd (2nd leg): 05/06/2019 23:15 | Winner: Cruzeiro | ||||
| 1st(1st leg) | Fortaleza | - | Athletico Paranaense | 0:0 (0:0) | ||
| 2nd (2nd leg) | Athletico Paranaense | - | Fortaleza | 1:0 (0:0) | ||
| 1st(1st leg): 16/05/2019 23:15 | 2nd (2nd leg): 05/06/2019 23:15 | Winner: Athletico Paranaense | ||||
| 1st(1st leg) | Sampaio Corrêa - MA | - | Palmeiras | 0:1 (0:0) | ||
| 2nd (2nd leg) | Palmeiras | - | Sampaio Corrêa - MA | 2:0 (1:0) | ||
| 1st(1st leg): 22/05/2019 23:15 | 2nd (2nd leg): 31/05/2019 00:00 | Winner: Palmeiras | ||||
| 1st(1st leg) | Juventude - RS | - | Grêmio Porto Alegre | 0:0 (0:0) | ||
| 2nd (2nd leg) | Grêmio Porto Alegre | - | Juventude - RS | 3:0 (1:0) | ||
| 1st(1st leg): 23/05/2019 01:30 | 2nd (2nd leg): 30/05/2019 01:30 | Winner: Grêmio Porto Alegre | ||||
| 1st(1st leg) | São Paulo FC | - | Bahia - BA | 0:1 (0:0) | ||
| 2nd (2nd leg) | Bahia - BA | - | São Paulo FC | 1:0 (0:0) | ||
| 1st(1st leg): 23/05/2019 01:30 | 2nd (2nd leg): 30/05/2019 01:30 | Winner: Bahia - BA | ||||
| 1st(1st leg) | Internacional | - | Paysandu - PA | 3:1 (1:0) | ||
| 2nd (2nd leg) | Paysandu - PA | - | Internacional | 0:1 (0:0) | ||
| 1st(1st leg): 24/05/2019 00:00 | 2nd (2nd leg): 29/05/2019 23:15 | Winner: Internacional | ||||
