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| 1st(1st leg) | Fluminense RJ | - | Flamengo RJ | 0:0 (0:0) | ||
| 2nd (2nd leg) | Flamengo RJ | - | Fluminense RJ | 2:0 (1:0) | ||
| 1st(1st leg): 17/05/2023 01:00 | 2nd (2nd leg): 02/06/2023 00:00 | Winner: Flamengo RJ | ||||
| 1st(1st leg) | Santos FC | - | Bahia - BA | 0:0 (0:0) | ||
| 2nd (2nd leg) | Bahia - BA | - | Santos FC | 4:3 (0:0, 1:1) pso | ||
| 1st(1st leg): 17/05/2023 23:00 | 2nd (2nd leg): 31/05/2023 23:00 | Winner: Bahia - BA | ||||
| 1st(1st leg) | Palmeiras | - | Fortaleza - CE | 3:0 (2:0) | ||
| 2nd (2nd leg) | Fortaleza - CE | - | Palmeiras | 1:0 (0:0) | ||
| 1st(1st leg): 17/05/2023 23:00 | 2nd (2nd leg): 31/05/2023 23:00 | Winner: Palmeiras | ||||
| 1st(1st leg) | Grêmio Porto Alegre | - | Cruzeiro | 1:1 (0:1) | ||
| 2nd (2nd leg) | Cruzeiro | - | Grêmio Porto Alegre | 0:1 (0:1) | ||
| 1st(1st leg): 17/05/2023 23:30 | 2nd (2nd leg): 01/06/2023 00:00 | Winner: Grêmio Porto Alegre | ||||
| 1st(1st leg) | Sport Recife - PE | - | São Paulo FC | 0:2 (0:0) | ||
| 2nd (2nd leg) | São Paulo FC | - | Sport Recife - PE | 5:3 (5:3, 5:3) pso | ||
| 1st(1st leg): 18/05/2023 00:00 | 2nd (2nd leg): 01/06/2023 23:30 | Winner: São Paulo FC | ||||
| 1st(1st leg) | Atlético Mineiro | - | Corinthians SP | 2:0 (0:0) | ||
| 2nd (2nd leg) | Corinthians SP | - | Atlético Mineiro | 3:1 (1:0, 2:0) pso | ||
| 1st(1st leg): 18/05/2023 01:30 | 2nd (2nd leg): 01/06/2023 01:30 | Winner: Corinthians SP | ||||
| 1st(1st leg) | América - MG | - | Internacional | 2:0 (0:0) | ||
| 2nd (2nd leg) | Internacional | - | América - MG | 4:5 (3:0, 3:1) pso | ||
| 1st(1st leg): 18/05/2023 01:30 | 2nd (2nd leg): 01/06/2023 01:30 | Winner: América - MG | ||||
| 1st(1st leg) | Athletico Paranaense | - | Botafogo - RJ | 3:2 (0:2) | ||
| 2nd (2nd leg) | Botafogo - RJ | - | Athletico Paranaense | 2:4 (1:0, 1:0) pso | ||
| 1st(1st leg): 18/05/2023 01:30 | 2nd (2nd leg): 01/06/2023 01:30 | Winner: Athletico Paranaense | ||||
