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| 1st(1st leg) | Santos FC | - | Corinthians SP | 0:2 (0:1) | ||
| 2nd (2nd leg) | Corinthians SP | - | Santos FC | 4:3 (2:3) | ||
| 1st(1st leg): 29/08/2023 23:00 | 2nd (2nd leg): 05/09/2023 23:00 | Winner: Corinthians SP | ||||
| 1st(1st leg) | Vasco da Gama | - | Fluminense RJ | 3:3 (1:1) | ||
| 2nd (2nd leg) | Fluminense RJ | - | Vasco da Gama | 4:0 (0:0) | ||
| 1st(1st leg): 30/08/2023 01:30 | 2nd (2nd leg): 05/09/2023 00:00 | Winner: Fluminense RJ | ||||
| 1st(1st leg) | Sampaio Corrêa - MA | - | Porto Velho EC - RO | 2:1 (1:1) | ||
| 2nd (2nd leg) | Porto Velho EC - RO | - | Sampaio Corrêa - MA | 1:1 (0:1) | ||
| 1st(1st leg): 30/08/2023 19:00 | 2nd (2nd leg): 07/09/2023 20:00 | Winner: Sampaio Corrêa - MA | ||||
| 1st(1st leg) | CEFAT - CE | - | Bahia - BA | 0:0 (0:0) | ||
| 2nd (2nd leg) | Bahia - BA | - | CEFAT - CE | 3:0 (1:0) | ||
| 1st(1st leg): 30/08/2023 19:00 | 2nd (2nd leg): 07/09/2023 19:00 | Winner: Bahia - BA | ||||
| 1st(1st leg) | Sport Recife - PE | - | CSA - AL | 1:1 (1:0) | ||
| 2nd (2nd leg) | CSA - AL | - | Sport Recife - PE | 1:0 (0:0) | ||
| 1st(1st leg): 30/08/2023 19:00 | 2nd (2nd leg): 06/09/2023 19:00 | Winner: CSA - AL | ||||
| 1st(1st leg) | Grêmio Porto Alegre | - | Athletico Paranaense | 2:1 (1:0) | ||
| 2nd (2nd leg) | Athletico Paranaense | - | Grêmio Porto Alegre | 0:0 (0:0) | ||
| 1st(1st leg): 30/08/2023 19:00 | 2nd (2nd leg): 05/09/2023 19:00 | Winner: Grêmio Porto Alegre | ||||
| 1st(1st leg) | Cruzeiro | - | América - MG | 2:0 (1:0) | ||
| 2nd (2nd leg) | América - MG | - | Cruzeiro | 0:2 (0:1) | ||
| 1st(1st leg): 31/08/2023 23:00 | 2nd (2nd leg): 06/09/2023 23:00 | Winner: Cruzeiro | ||||
| 1st(1st leg) | São Raimundo - RR | - | Remo - PA | 0:4 (0:0) | ||
| 2nd (2nd leg) | Remo - PA | - | São Raimundo - RR | 6:0 (4:0) | ||
| 1st(1st leg): 01/09/2023 00:00 | 2nd (2nd leg): 09/09/2023 23:00 | Winner: Remo - PA | ||||
