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| 1st(1st leg) | Real Sociedad | - | FC Barcelona | 0:1 | ||
| 2nd (2nd leg) | FC Barcelona | - | Real Sociedad | 0:0 | ||
| 1st(1st leg): 17/05/2014 | 2nd (2nd leg): 25/05/2014 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Atlético Madrid | - | Rayo Vallecano | 0:0 (0:0) | ||
| 2nd (2nd leg) | Rayo Vallecano | - | Atlético Madrid | 3:2 pso | ||
| 1st(1st leg): 18/05/2014 | 2nd (2nd leg): 25/05/2014 | Winner: Rayo Vallecano | ||||
| 1st(1st leg) | Sporting de Huelva | - | Levante UD | 1:0 | ||
| 2nd (2nd leg) | Levante UD | - | Sporting de Huelva | 2:0 | ||
| 1st(1st leg): 18/05/2014 | 2nd (2nd leg): 25/05/2014 | Winner: Levante UD | ||||
| 1st(1st leg) | Athletic Bilbao | - | Valencia CF | 0:0 | ||
| 2nd (2nd leg) | Valencia CF | - | Athletic Bilbao | 1:4 | ||
| 1st(1st leg): 18/05/2014 | 2nd (2nd leg): 25/05/2014 | Winner: Athletic Bilbao | ||||
