Copa Libertadores   M. W D L goals
  at home 2 1 1 0 4 : 1
  Away 3 1 1 1 2 : 2
  5 2 2 1 6 : 3
overall   M. W D L goals
  at home 2 1 1 0 4 : 1
  Away 3 1 1 1 2 : 2
  Neutral Place 0 0 0 0 0 : 0
  5 2 2 1 6 : 3
Copa Libertadores
2024 Group B Barcelona - São Paulo FC 0:2 (0:1)
1992 Semi-finals Barcelona - São Paulo FC 2:0 (0:0)
1992 Semi-finals São Paulo FC - Barcelona 3:0 (3:0)
1972 Group B São Paulo FC - Barcelona 1:1 (1:1)
1972 Group B Barcelona - São Paulo FC 0:0 (0:0)

For games that were decided on penalties the score after 120 minutes will be included in the ranking