Champions League   M. W D L goals
  at home 2 2 0 0 4 : 1
  Away 2 1 0 1 4 : 3
  4 3 0 1 8 : 4
overall   M. W D L goals
  at home 2 2 0 0 4 : 1
  Away 2 1 0 1 4 : 3
  Neutral Place 0 0 0 0 0 : 0
  4 3 0 1 8 : 4
Champions League
2006/2007 Group D Valencia CF - Olympiakos Piraeus 2:0 (1:0)
2006/2007 Group D Olympiakos Piraeus - Valencia CF 2:4 (1:2)
2000/2001 Preliminary Gr. C Olympiakos Piraeus - Valencia CF 1:0 (0:0)
2000/2001 Preliminary Gr. C Valencia CF - Olympiakos Piraeus 2:1 (2:0)

For games that were decided on penalties the score after 120 minutes will be included in the ranking