| Copa Libertadores | M. | W | D | L | goals | |||
| at home | 2 | 0 | 1 | 1 | 1 | : | 2 | |
| Away | 2 | 0 | 0 | 2 | 3 | : | 15 | |
| ∑ | 4 | 0 | 1 | 3 | 4 | : | 17 | |
| overall | M. | W | D | L | goals | |||
| at home | 2 | 0 | 1 | 1 | 1 | : | 2 | |
| Away | 2 | 0 | 0 | 2 | 3 | : | 15 | |
| Neutral Place | 0 | 0 | 0 | 0 | 0 | : | 0 | |
| ∑ | 4 | 0 | 1 | 3 | 4 | : | 17 | |
| Copa Libertadores | |||||
| 1972 | Group 5 | Peñarol | - | Valencia FC | 4:1 (2:0) |
| 1972 | Group 5 | Valencia FC | - | Peñarol | 1:2 (1:2) |
| 1970 | Group 2 | Peñarol | - | Valencia FC | 11:2 (5:0) |
| 1970 | Group 2 | Valencia FC | - | Peñarol | 0:0 (0:0) |
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For games that were decided on penalties the score after 120 minutes will be included in the ranking |
Venezuela