1. Round | 06/08/2022 | VfL Bochum | - | 1. FSV Mainz 05 | 1:2 | ||||
2. Round | 14/08/2022 | 1. FSV Mainz 05 | - | 1. FC Union Berlin | 0:0 | ||||
3. Round | 20/08/2022 | FC Augsburg | - | 1. FSV Mainz 05 | 1:2 | ||||
4. Round | 27/08/2022 | 1. FSV Mainz 05 | - | Bayer Leverkusen | 0:3 | ||||
5. Round | 04/09/2022 | Bor. Mönchengladbach | - | 1. FSV Mainz 05 | 0:1 | ||||
6. Round | 10/09/2022 | 1899 Hoffenheim | - | 1. FSV Mainz 05 | 4:1 | ||||
8. Round | 01/10/2022 | SC Freiburg | - | 1. FSV Mainz 05 | 2:1 | ||||
9. Round | 08/10/2022 | 1. FSV Mainz 05 | - | RB Leipzig | 1:1 | ||||
12. Round | 29/10/2022 | Bayern München | - | 1. FSV Mainz 05 | 6:2 | ||||
13. Round | 05/11/2022 | 1. FSV Mainz 05 | - | VfL Wolfsburg | 0:3 | ||||
26. Round | 01/04/2023 | RB Leipzig | - | 1. FSV Mainz 05 | 0:3 | ||||
31. Round | 05/05/2023 | 1. FSV Mainz 05 | - | FC Schalke 04 | 2:3 | ||||
32. Round | 13/05/2023 | Eintracht Frankfurt | - | 1. FSV Mainz 05 | 3:0 |