| #1 | 23/01/1963 | Bulgaria | - | Portugal | 1:0 | ||||
| #2 | 29/04/1964 | Switzerland | - | Portugal | 2:3 |  |
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| #3 | 03/05/1964 | Belgium | - | Portugal | 1:2 | ||||
| #4 | 17/05/1964 | Portugal | - | England | 3:4 | |
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| #5 | 31/05/1964 | Portugal | - | Argentina | 0:2 | ||||
| #6 | 04/06/1964 | Portugal | - | England | 1:1 |  |
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| #7 | 15/11/1964 | Portugal | - | Spain | 2:1 | ||||
| #8 | 24/01/1965 | Portugal | - | Turkey | 5:1 | ||||
| #9 | 19/04/1965 | Turkey | - | Portugal | 0:1 | ||||
| #10 | 25/04/1965 | CSSR | - | Portugal | 0:1 | ||||
| #11 | 13/06/1965 | Portugal | - | Romania | 2:1 | ||||
| #12 | 31/10/1965 | Portugal | - | CSSR | 0:0 | ||||
| #13 | 21/11/1965 | Romania | - | Portugal | 2:0 | ||||
| #14 | 12/06/1966 | Portugal | - | Norway | 4:0 | ||||
| #15 | 18/06/1966 | Scotland | - | Portugal | 0:1 | |
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| #16 | 21/06/1966 | Denmark | - | Portugal | 1:3 | |
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| #17 | 26/06/1966 | Portugal | - | Uruguay | 3:0 | |
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| #18 | 03/07/1966 | Portugal | - | Romania | 1:0 | |
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| #19 | 13/07/1966 | Portugal | - | Hungary | 3:1 | |
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| #20 | 16/07/1966 | Portugal | - | Bulgaria | 3:0 | |
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| #21 | 19/07/1966 | Portugal | - | Brazil | 3:1 | ||||
| #22 | 23/07/1966 | Portugal | - | North Korea | 5:3 | ||||
| #23 | 26/07/1966 | England | - | Portugal | 2:1 | ||||
| #24 | 28/07/1966 | Portugal | - | USSR | 2:1 | |
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| #25 | 12/11/1967 | Portugal | - | Norway | 2:1 | |
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| #26 | 26/11/1967 | Bulgaria | - | Portugal | 1:0 | ||||
| #27 | 17/12/1967 | Portugal | - | Bulgaria | 0:0 | ||||
| #28 | 11/12/1968 | Greece | - | Portugal | 4:2 | ||||
| #29 | 16/04/1969 | Portugal | - | Switzerland | 0:2 | ||||
| #30 | 12/10/1969 | Romania | - | Portugal | 1:0 | ||||
| #31 | 10/05/1970 | Portugal | - | Italy | 1:2 | ||||
| #32 | 21/11/1971 | Portugal | - | Belgium | 1:1 | ||||
| #33 | 13/10/1973 | Portugal | - | Bulgaria | 2:2 |
Portugal