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| 1st(1st leg) | Atlético Mineiro | - | Palmeiras | 1:1 (0:0) | ||
| 2nd (2nd leg) | Palmeiras | - | Atlético Mineiro | 2:0 (1:0) | ||
| 1st(1st leg): 27/10/2010 22:45 | 2nd (2nd leg): 11/11/2010 00:00 | Winner: Palmeiras | ||||
| 1st(1st leg) | Goiás - GO | - | Avaí - SC | 2:2 (1:0) | ||
| 2nd (2nd leg) | Avaí - SC | - | Goiás - GO | 0:1 (0:1) | ||
| 1st(1st leg): 28/10/2010 01:00 | 2nd (2nd leg): 11/11/2010 22:00 | Winner: Goiás - GO | ||||
| 1st(1st leg) | Newell's Old Boys | - | LDU Quito | 0:0 (0:0) | ||
| 2nd (2nd leg) | LDU Quito | - | Newell's Old Boys | 1:0 (0:0) | ||
| 1st(1st leg): 03/11/2010 00:15 | 2nd (2nd leg): 11/11/2010 02:20 | Winner: LDU Quito | ||||
| 1st(1st leg) | Deportes Tolima | - | Independiente | 2:2 (1:1) | ||
| 2nd (2nd leg) | Independiente | - | Deportes Tolima | 0:0 (0:0) | ||
| 1st(1st leg): 04/11/2010 00:15 | 2nd (2nd leg): 12/11/2010 00:30 | Winner: Independiente | ||||
