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| 25/09/2007 | 19:45 | Falkirk FC | - | Dundee United | 0:1 | |
| 19:45 | Hamilton Academical | - | Kilmarnock FC | 2:0 | ||
| 19:45 | Heart of Midlothian | - | Dunfermline Athletic | 4:1 aet | ||
| 19:45 | Inverness CT | - | Gretna FC | 3:0 | ||
| 26/09/2007 | 19:45 | Dundee FC | - | Celtic FC | 1:2 | |
| 19:45 | East Fife FC | - | Rangers FC | 0:4 | ||
| 19:45 | Hibernian FC | - | Motherwell FC | 2:4 | ||
| 19:45 | Partick Thistle | - | Aberdeen FC | 0:2 |
