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| 21/09/2010 | 19:45 | Rangers FC | - | Dunfermline Athletic | 7:2 (3:1) | |
| 19:45 | Falkirk FC | - | Heart of Midlothian | 4:3 (2:0) | ||
| 19:45 | St. Johnstone FC | - | Queen Of The South | 3:0 (0:0) | ||
| 19:45 | Brechin City FC | - | Motherwell FC | 0:2 (0:1) | ||
| 22/09/2010 | 19:30 | Ross County FC | - | Dundee United | 1:2 (0:0, 1:1) aet | |
| 19:45 | Kilmarnock FC | - | Hibernian FC | 3:1 (1:1) | ||
| 19:45 | Aberdeen FC | - | Raith Rovers | 3:2 (1:2) | ||
| 19:45 | Celtic FC | - | Inverness CT | 6:0 (3:0) |
