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| 25/09/2012 | 19:45 | Celtic FC | - | Raith Rovers | 4:1 (2:1) | |
| 19:45 | St. Mirren FC | - | Hamilton Academical | 1:0 (0:0) | ||
| 19:45 | Heart of Midlothian | - | Livingston FC | 3:1 (1:0) | ||
| 19:45 | St. Johnstone FC | - | Queen's Park FC | 4:1 (2:1) | ||
| 19:45 | Stenhousemuir FC | - | Inverness CT | 5:6 (1:1, 1:1, 1:1) pso | ||
| 19:45 | Queen Of The South | - | Dundee United | 0:1 (0:1) | ||
| 26/09/2012 | 19:15 | Rangers FC | - | Motherwell FC | 2:0 (0:0) | |
| 19:45 | Dunfermline Athletic | - | Aberdeen FC | 0:1 (0:0) |
