WC Qualifiers Africa   M. W D L goals
  at home 1 1 0 0 2 : 0
  Away 1 0 0 1 0 : 4
  2 1 0 1 2 : 4
Africa Cup Qual.   M. W D L goals
  at home 1 1 0 0 2 : 1
  Away 2 0 1 1 4 : 6
  Neutral Place 1 0 0 1 0 : 2
  4 1 1 2 6 : 9
overall   M. W D L goals
  at home 2 2 0 0 4 : 1
  Away 3 0 1 2 4 : 10
  Neutral Place 1 0 0 1 0 : 2
  6 2 1 3 8 : 13
WC Qualifiers Africa
2000/2001 1. Round Sierra Leone - São Tomé and Príncipe 4:0 (2:0)
2000/2001 1. Round São Tomé and Príncipe - Sierra Leone 2:0 (1:0)
Africa Cup Qual.
2022-2023 Group A São Tomé and Príncipe - Sierra Leone 0:2 (0:2)
2022-2023 Group A Sierra Leone - São Tomé and Príncipe 2:2 (0:1)
2013 1. Round Sierra Leone - São Tomé and Príncipe 4:2 (4:1)
2013 1. Round São Tomé and Príncipe - Sierra Leone 2:1 (0:0)

For games that were decided on penalties the score after 120 minutes will be included in the ranking