1. Round | 06/08/2022 | VfL Bochum | - | 1. FSV Mainz 05 | 1:2 | ||||
2. Round | 14/08/2022 | 1. FSV Mainz 05 | - | 1. FC Union Berlin | 0:0 | ||||
3. Round | 20/08/2022 | FC Augsburg | - | 1. FSV Mainz 05 | 1:2 | ||||
5. Round | 04/09/2022 | Bor. Mönchengladbach | - | 1. FSV Mainz 05 | 0:1 | ||||
7. Round | 16/09/2022 | 1. FSV Mainz 05 | - | Hertha BSC | 1:1 | ![]() |
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34. Round | 27/05/2023 | Borussia Dortmund | - | 1. FSV Mainz 05 | 2:2 |