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| 1st(1st leg) | Athletico Paranaense | - | CF Pachuca | 0:1 (0:0) | ||
| 2nd (2nd leg) | CF Pachuca | - | Athletico Paranaense | 4:1 (0:1) | ||
| 1st(1st leg): 15/11/2006 | 2nd (2nd leg): 22/11/2006 | Winner: CF Pachuca | ||||
| 1st(1st leg) | Colo-Colo | - | Deportivo Toluca | 2:1 (2:1) | ||
| 2nd (2nd leg) | Deportivo Toluca | - | Colo-Colo | 0:2 (0:1) | ||
| 1st(1st leg): 16/11/2006 | 2nd (2nd leg): 21/11/2006 | Winner: Colo-Colo | ||||
