Bundesliga   M. W D L goals
  at home 3 0 3 0 1 : 1
  Away 3 1 1 1 8 : 4
  6 1 4 1 9 : 5
DFB-Pokal   M. W D L goals
  Neutral Place 1 0 0 1 0 : 2
  1 0 0 1 0 : 2
overall   M. W D L goals
  at home 3 0 3 0 1 : 1
  Away 3 1 1 1 8 : 4
  Neutral Place 1 0 0 1 0 : 2
  7 1 4 2 9 : 7
Bundesliga
2022/2023 21. Round 1. FC Union Berlin - FC Schalke 04 0:0 (0:0)
2022/2023 4. Round FC Schalke 04 - 1. FC Union Berlin 1:6 (1:3)
2020/2021 21. Round 1. FC Union Berlin - FC Schalke 04 0:0 (0:0)
2020/2021 4. Round FC Schalke 04 - 1. FC Union Berlin 1:1 (0:0)
2019/2020 30. Round 1. FC Union Berlin - FC Schalke 04 1:1 (1:1)
2019/2020 13. Round FC Schalke 04 - 1. FC Union Berlin 2:1 (1:1)
DFB-Pokal
2000/2001 Final 1. FC Union Berlin - FC Schalke 04 0:2 (0:0)

For games that were decided on penalties the score after 120 minutes will be included in the ranking