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| 1st(1st leg) | Leixões SC | - | Vitória Setúbal | 0:1 | ||
| 2nd (2nd leg) | Vitória Setúbal | - | Leixões SC | 1:1 | ||
| 1st(1st leg): 08/09/2012 17:00 | 2nd (2nd leg): 19/09/2012 18:00 | Winner: Vitória Setúbal | ||||
| 1st(1st leg) | Sporting Covilhã | - | Académica de Coimbra | 2:0 | ||
| 2nd (2nd leg) | Académica de Coimbra | - | Sporting Covilhã | 3:2 pso | ||
| 1st(1st leg): 08/09/2012 21:00 | 2nd (2nd leg): 14/10/2012 18:00 | Winner: Académica de Coimbra | ||||
| 1st(1st leg) | Naval 1° de Maio | - | Gil Vicente | 1:1 | ||
| 2nd (2nd leg) | Gil Vicente | - | Naval 1° de Maio | 1:2 | ||
| 1st(1st leg): 09/09/2012 18:00 | 2nd (2nd leg): 13/10/2012 16:00 | Winner: Naval 1° de Maio | ||||
| 1st(1st leg) | União da Madeira | - | GD Estoril | 0:1 | ||
| 2nd (2nd leg) | GD Estoril | - | União da Madeira | 1:1 | ||
| 1st(1st leg): 13/09/2012 17:00 | 2nd (2nd leg): 31/10/2012 16:00 | Winner: GD Estoril | ||||
| 1st(1st leg) | CD Feirense | - | Moreirense FC | 1:0 | ||
| 2nd (2nd leg) | Moreirense FC | - | CD Feirense | 4:2 pso | ||
| 1st(1st leg): 26/09/2012 15:00 | 2nd (2nd leg): 31/10/2012 16:00 | Winner: Moreirense FC | ||||
| 1st(1st leg) | CD Santa Clara | - | SC Beira-Mar | 0:1 | ||
| 2nd (2nd leg) | SC Beira-Mar | - | CD Santa Clara | 2:1 | ||
| 1st(1st leg): 26/09/2012 18:00 | 2nd (2nd leg): 31/10/2012 17:00 | Winner: SC Beira-Mar | ||||
| 1st(1st leg) | SC Freamunde | - | Rio Ave FC | 2:3 | ||
| 2nd (2nd leg) | Rio Ave FC | - | SC Freamunde | 0:0 | ||
| 1st(1st leg): 26/09/2012 20:30 | 2nd (2nd leg): 31/10/2012 18:00 | Winner: Rio Ave FC | ||||
| 1st(1st leg) | CD Aves | - | Paços de Ferreira | 0:1 | ||
| 2nd (2nd leg) | Paços de Ferreira | - | CD Aves | 1:0 | ||
| 1st(1st leg): 03/10/2012 16:00 | 2nd (2nd leg): 31/10/2012 16:00 | Winner: Paços de Ferreira | ||||
