| 2. Round | 18/09/2020 | Derby County U23 | - | Liverpool FC U23 | 2:1 | ||||
| 5. Round | 17/10/2020 | Brighton & Hove Albion U23 | - | Liverpool FC U23 | 1:0 | ||||
| 6. Round | 24/10/2020 | Liverpool FC U23 | - | Chelsea FC U23 | 3:1 | ||||
| 7. Round | 30/10/2020 | Arsenal FC U23 | - | Liverpool FC U23 | 0:1 | ||||
| 8. Round | 06/11/2020 | West Ham United U23 | - | Liverpool FC U23 | 2:4 | ||||
| 9. Round | 21/11/2020 | Liverpool FC U23 | - | Southampton FC U23 | 0:0 | ||||
| 10. Round | 28/11/2020 | Liverpool FC U23 | - | Manchester City U23 | 2:7 | ||||
| 11. Round | 12/12/2020 | Liverpool FC U23 | - | Blackburn Rovers U23 | 1:2 | ||||
| 12. Round | 19/12/2020 | Liverpool FC U23 | - | Tottenham Hotspur U23 | 3:4 | ||||
| 20. Round | 27/02/2021 | Liverpool FC U23 | - | Arsenal FC U23 | 4:0 | ||||
| 15. Round | 07/03/2021 | Liverpool FC U23 | - | Derby County U23 | 1:4 | ||||
| 22. Round | 21/03/2021 | Southampton FC U23 | - | Liverpool FC U23 | 1:2 | ||||
| 18. Round | 04/04/2021 | Liverpool FC U23 | - | Brighton & Hove Albion U23 | 3:2 |
England