| 2. Round | 03/08/2013 | Sporting Charleroi | - | Waasland-Beveren | 1:1 |  |
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| 5. Round | 25/08/2013 | RSC Anderlecht | - | Sporting Charleroi | 5:2 | |
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| 6. Round | 01/09/2013 | Sporting Charleroi | - | KRC Genk | 1:1 | ||||
| 7. Round | 14/09/2013 | Oud-Heverlee Leuven | - | Sporting Charleroi | 0:0 | ||||
| 8. Round | 21/09/2013 | Sporting Charleroi | - | Cercle Brugge | 2:0 | ||||
| 12. Round | 27/10/2013 | SV Zulte Waregem | - | Sporting Charleroi | 1:1 |  |
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| 15. Round | 09/11/2013 | Sporting Charleroi | - | KAA Gent | 0:1 | ||||
| 16. Round | 23/11/2013 | Sporting Charleroi | - | RSC Anderlecht | 2:1 | ||||
| 27. Round | 22/02/2014 | Sporting Charleroi | - | SV Zulte Waregem | 3:2 | |
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| 29. Round | 08/03/2014 | Sporting Charleroi | - | Lierse SK (old) | 1:1 | ||||
| 30. Round | 16/03/2014 | KV Mechelen | - | Sporting Charleroi | 0:3 |
Ghana