| 4. Round | 29/10/2009 | Unión Deportiva Puertollano | - | Villarreal CF | 1:1 | ||||
| 4. Round | 10/11/2009 | Villarreal CF | - | Unión Deportiva Puertollano | 1:0 |
| 4. Round | 29/10/2009 | Unión Deportiva Puertollano | - | Villarreal CF | 1:1 | ||||
| 4. Round | 10/11/2009 | Villarreal CF | - | Unión Deportiva Puertollano | 1:0 |
| Addison Alves de Oliveira | |
| Born: | 20.03.1981 |
| Place of birth: |
Brasilia, 
Brazil |
| Nationality: |
Brazil
Spain |
| Height: | 177 cm |
| Weight: | 70 kg |
| Position(s): | Left Winger Centre Forward |
| Foot: | right |