| 2. Round | 17/07/2005 | FK Illichivets | - | Vorskla Poltava | 3:2 | ||||
| 3. Round | 23/07/2005 | Metalurh Donetsk | - | FK Illichivets | 0:0 | ||||
| 4. Round | 31/07/2005 | FK Illichivets | - | Chernomorets Odessa | 0:1 | ||||
| 6. Round | 21/08/2005 | FK Illichivets | - | Volyn Lutsk | 1:1 | ||||
| 7. Round | 29/08/2005 | Dnipro Dnipropetrovsk | - | FK Illichivets | 0:1 | ||||
| 8. Round | 11/09/2005 | FK Illichivets | - | FK Kharkiv | 2:1 | ||||
| 11. Round | 03/10/2005 | Shakhtar Donetsk | - | FK Illichivets | 6:0 | ||||
| 13. Round | 23/10/2005 | Arsenal Kiev | - | FK Illichivets | 0:2 | ||||
| 14. Round | 30/10/2005 | FK Illichivets | - | Stal Alchevsk | 3:0 | ||||
| 18. Round | 04/12/2005 | FK Illichivets | - | Metalurh Donetsk | 1:0 | ||||
| 19. Round | 08/12/2005 | Chernomorets Odessa | - | FK Illichivets | 1:2 | ||||
| 20. Round | 05/03/2006 | FK Illichivets | - | Dinamo Kiev | 1:2 | ||||
| 22. Round | 19/03/2006 | FK Illichivets | - | Dnipro Dnipropetrovsk | 0:0 | ||||
| 23. Round | 26/03/2006 | FK Kharkiv | - | FK Illichivets | 3:0 | ||||
| 27. Round | 22/04/2006 | Metalurg Zaporizhya | - | FK Illichivets | 2:1 | ||||
| 29. Round | 06/05/2006 | Stal Alchevsk | - | FK Illichivets | 1:0 | ||||
| 30. Round | 10/05/2006 | FK Illichivets | - | Zakarpattya Uzhgorod | 2:0 |
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