| 1. Round | 29/07/2006 | FC Unirea | - | Politehnica Iasi | 0:2 | ||||
| 2. Round | 06/08/2006 | CFR Cluj | - | FC Unirea | 4:0 | ||||
| 3. Round | 11/08/2006 | FC Unirea | - | Oţelul Galaţi | 1:0 | ||||
| 4. Round | 18/08/2006 | Farul Constanța | - | FC Unirea | 0:1 | ||||
| 5. Round | 25/08/2006 | Ceahlăul Piatra Neamt | - | FC Unirea | 2:1 |  |
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| 6. Round | 10/09/2006 | FC Unirea | - | National Bucureşti | 2:0 | ||||
| 7. Round | 16/09/2006 | Pandurii Târgu Jiu | - | FC Unirea | 1:0 | ||||
| 8. Round | 20/09/2006 | FC Unirea | - | Jiul Petroşani | 3:0 | ||||
| 9. Round | 23/09/2006 | SC FC Politehnica Timisoara | - | FC Unirea | 1:0 | ||||
| 10. Round | 01/10/2006 | FC Unirea | - | FC Universitatea Craiova | 1:2 |
Brazil