| 4. Round | 05/08/2023 | Atlético Huila | - | Alianza Petrolera | 0:0 | ||||
| 6. Round | 21/08/2023 | Independiente Medellín | - | Alianza Petrolera | 2:1 | ||||
| 7. Round | 23/08/2023 | Alianza Petrolera | - | La Equidad | 1:0 | ||||
| 1. Round | 06/09/2023 | Alianza Petrolera | - | Boyacá Chicó | 1:1 | ||||
| 10. Round | 12/09/2023 | Atlético Bucaramanga | - | Alianza Petrolera | 0:1 | ||||
| 11. Round | 15/09/2023 | Alianza Petrolera | - | Atlético Junior | 1:5 | ||||
| 12. Round | 17/09/2023 | Santa Fe | - | Alianza Petrolera | 0:1 | ||||
| 13. Round | 22/09/2023 | Jaguares de Córdoba | - | Alianza Petrolera | 0:0 | ||||
| 14. Round | 26/09/2023 | Alianza Petrolera | - | Once Caldas | 2:1 | ||||
| 15. Round | 02/10/2023 | Deportivo Cali | - | Alianza Petrolera | 1:0 | ||||
| 16. Round | 11/10/2023 | Alianza Petrolera | - | Atlético Bucaramanga | 1:0 |  |
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| 17. Round | 15/10/2023 | Águilas Doradas | - | Alianza Petrolera | 3:0 |  |
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| 18. Round | 23/10/2023 | Alianza Petrolera | - | Deportes Tolima | 0:1 | ||||
| 19. Round | 27/10/2023 | Atlético Nacional | - | Alianza Petrolera | 2:0 | |
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| 20. Round | 08/11/2023 | Alianza Petrolera | - | Deportivo Pereira | 2:1 |
Colombia